Molar enthalpies of formation and vaporization of t-butoxybutanes and thermodynamics of their synthesis from a butanol and 2-methylpropene. I. Equilibria of synthesis reactions of t-butoxybutanes in the liquid phase

Article abstract of DOI:10.1016/S0021-9614(05)80290-3

The equilibria of the synthesis of 1-t-butoxybutane (I), 2-methyl-1-t-butoxypropane (II), and 1-methyl-1-t-butoxypropane (III) from 2-methylpropene (IV), and butan-1-ol (V), 2-methyl-propan-1-ol (VI), and butan-2-ol (VII) in the liquid phase were investigated at temperatures from 315 K to 423 K.On the basis of experimental equilibrium constants found for n(C4H9OH)/n<(CH3)2C:CH2> = 4, values of Δ_rH_m^deg and Δ_rS_m^deg were calculated.The following results were obtained

Full text of DOI:10.1016/S0021-9614(05)80290-3

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