Attempted preparation of 5,5-difluoro-1,4-diphenylbicyclo[2.1.0]pentane - Serendipitous synthesis of 1,3-difluoro-2,4-diphenylbenzene

DOI: 10.1016/S0040-4039(00)76217-4

Source and publish data:

Tetrahedron Letters p. 1357 - 1360 (1994)

Update date:2022-08-17

Topics:

Authors:

Lewis Lewis

Borden Borden

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)76217-4

Addition of difluorocarbene to 1,2-diphenylcyclobutene, using PhHgCF₃, results in formation of 1,3-difluoro-2,4-diphenylbenzene. A mechanism for this reaction is proposed.

Full text of DOI:10.1016/S0040-4039(00)76217-4

Products guided by the article

Product name:1,2-Diphenylcyclobutene

Cas No:3306-02-3

R&D Labs maybe for 3306-02-3

Mashilabs(shanghai)Co.,ltd

Contact:+86-21-54391580

Address:Room 502,No.65,Lane 2388 Hongxin Road,Shanghai,China
zhejiang huangyan wanfeng pharm chem co.ltd

Contact:+86-576- 84160728

Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China
Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China

Relevant to this article

Synthesis of solenopsin B via stereoselective reduction of Bicyclic N,O-ketals

Doi:10.1016/S0040-4039(00)79891-1
(1991)
Magnetic copper ferrite nanoparticles/TEMPO catalyzed selective oxidation of activated alcohols to aldehydes under ligand- and base-free conditions in water

Doi:10.1039/c4ra14152k
(2014)
Photoactivated racemization catalyst for dynamic kinetic resolution of secondary alcohols

Doi:10.1021/jo1009036
(2010)
A tetrathiafulvalene-functionalized schiff base macrocycle: Synthesis, electrochemical, and photophysical properties

Doi:10.1016/j.tet.2011.01.011
(2011)
Doi:10.1007/BF00913772
(1968)
Halogenation using quaternary ammonium polyhalides XXVII.¹ chloroiodination of alkenes with benzyltrimethyl-ammonium dichloroiodate

Doi:10.1246/bcsj.63.3033
(1990)

Article Doi