Attempted preparation of 5,5-difluoro-1,4-diphenylbicyclo[2.1.0]pentane - Serendipitous synthesis of 1,3-difluoro-2,4-diphenylbenzene

DOI: 10.1016/S0040-4039(00)76217-4

Source and publish data:

Tetrahedron Letters p. 1357 - 1360 (1994)

Update date:2022-08-17

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Authors:

Lewis Lewis

Borden Borden

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Article abstract of DOI:10.1016/S0040-4039(00)76217-4

Addition of difluorocarbene to 1,2-diphenylcyclobutene, using PhHgCF₃, results in formation of 1,3-difluoro-2,4-diphenylbenzene. A mechanism for this reaction is proposed.

Full text of DOI:10.1016/S0040-4039(00)76217-4

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