DARSTELLUNG VON PRIMAEREN ALKYLFLUORIDEN UNTER EINSATZ DER PHASEN TRANSFER KATALYSE

Article abstract of DOI:10.1016/S0022-1139(00)81165-3

The influence of the following factors on the solid-liquid PTC fluorination reaction of primary alkyl halides was studied: the catalyst quantity applied, the water content of solid alkali fluoride salt, and the type of catalyst.Kinetic curves at different temperatures were found for the reaction.The maximum yield is a function of the interaction of two parallel running reactions, namely the direct fluorination reaction and the catalyst decomposition.