The Reaction of Nitrogen Dioxide with N-Benzylidene-t-butylamine N-Oxide. Formation of a White Solid Adduct and Its Properties

DOI: 10.1246/cl.1992.207

Source and publish data:

Chemistry Letters p. 207 - 210 (1992)

Update date:2022-08-11

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Authors:

Sonokawa, Koji

Machida, Hidenori

Sakakibara, Kazuhisa

Hirota, Minoru

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Article abstract of DOI:10.1246/cl.1992.207

The reaction of N-benzylidene-t-butylamine N-oxide (PBN) with NO2 gave white diamagnetic solid C11H16N2O4 in addition to greenish blue free radical species.The white solid was shown to decompose quantitatively into the starting PBN and nitric acid when it was dissolved in water.

Full text of DOI:10.1246/cl.1992.207

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