Synthesis and structure of 5-carbaphosphatrane

Article abstract of DOI:10.1080/10426500108546641

1-Hydro-5-carbaphosphatrane 4, the first 5-carbon analog of a phosphatrane, was synthesized. X-ray crystallographic analysis showed that it has a typical TBP structure and that it is a 10-P-5 phosphorane in a perfectly "anti-apicophilic" arrangement.

Full text of DOI:10.1080/10426500108546641

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Phosphorus, Sulfur,
and Silicon and the
Related Elements
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Synthesis and
Structure of 5-
Carbaphosphatrane
Junji Kobayashi , Kei Goto &
Takayuki Kawashima
a Department of Chemistry,
Graduate School of Science , The
University of Tokyo , 7–3–1 Hongo,
Bunkyo-ku, Tokyo 113–0033, Japan
b Department of Chemistry,
Graduate School of Science , The
University of Tokyo , 7–3–1 Hongo,
Bunkyo-ku, Tokyo 113–0033, Japan
c Department of Chemistry,
Graduate School of Science , The
University of Tokyo , 7–3–1 Hongo,
Bunkyo-ku, Tokyo 113–0033, Japan
Published online: 02 Apr 2008.

To cite this article: Junji Kobayashi , Kei Goto & Takayuki
Kawashima (2001) Synthesis and Structure of 5-Carbaphosphatrane,
Phosphorus, Sulfur, and Silicon and the Related Elements, 169:1,
273-276, DOI: 10.1080/10426500108546641
To link to this article: http://
dx.doi.org/10.1080/10426500108546641
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