Journal of the Chemical Society. Chemical communications p. 659 - 661 (1987)
Update date:2022-08-11
Topics:
Tanase, Tomoaki
Shimizu, Fumihiko
Kuse, Manabu
Yano, Shigenobu
Yoshikawa, Sadao
Hidai, Masanobu
Aldoses are epimerized at C-2 by combinations of certain metals (Ni2+, Co2+, Ca2+, and Sr2+) and diamines (N,N,N'-trimethylethylenediamine and N,N,N',N'-tetramethylethylenediamine), and a 13C n.m.r. study reveals that a novel rearrangement of the carbon skeleton, the exchange of C-1 and C-2 atoms by inversion of the C-1-C-2 aldose fragment, is involved in this reaction.
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