Suicide inactivation of cytochrome P-450 model compounds by terminal olefins. 1. A mechanistic study of heme N-alkylation and expoxidation

DOI: 10.1021/ja00164a021

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Journal of the American Chemical Society p. 2977 - 2986 (1990)

Update date:2022-08-10

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Authors:

Collman Collman

Hampton Hampton

Brauman Brauman

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Article abstract of DOI:10.1021/ja00164a021

Synthetic iron porphyrins are found to be useful models for the suicide inactivation of cytochrome P-450. The epoxidation of 1-alkenes, 1,1-disubstituted alkenes, and styrenes by meso-[tetrakis(2,6-dichlorophenyl)porphinatoiron(III) chloride [Fe(OCP)Cl] r

Full text of DOI:10.1021/ja00164a021

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