Tetrahedron p. 6319 - 6328 (1999)
Update date:2022-08-16
Topics:
Yufit, Sergei S.
Zinovyev, Sergei S.
The phenomenon of initial exponential burst (IB) on kinetic curves in the reaction with solid salts was observed in the study on the S(N)2 substitution reaction of 2-octylmesylate with potassium halides under phase- transfer catalysis (PTC) conditions in liquid-liquid (l/l) and solid-liquid (s/l) systems. The mechanistic scheme describing the IB phenomenon in application to s/l PTC has been developed from the analysis of IB kinetic model known in enzyme kinetics.
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