
Tetrahedron p. 4175 - 4180 (1996)
Update date:2022-08-28
Topics:
Chapuzet, Jean-Marc
Beauchemin, Sophie
Daoust, Benoit
Lessard, Jean
The methanolysis of allylic alcohols, benzylic tertiary alcohols and epoxides in the presence of a catalytic amount of ceric ammonium nitrate (CAN) is shown to be catalysed by protons generated from the oxidation of methanol. This reaction is also catalysed by Lewis acids.
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