Some features of an SmI2-(Me2N)3P-THF system. Transformation of esters into dimethylamides

DOI: 10.1007/BF02494683

Source and publish data:

Russian Chemical Bulletin p. 329 - 331 (2000)

Update date:2022-08-18

Topics:

Authors:

Ivanova Ivanova

Shainurova

Miftakhov

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Article abstract of DOI:10.1007/BF02494683

Sm¹¹-intermediates generated upon addition of (Me₂N)₃P to a solution of SmI₂ in THF exhibit the properties of a single-electron reducing agent and an N-nucleophile. In particular, N,N-dimethylamides are formed from esters.

Full text of DOI:10.1007/BF02494683

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