cis-Stereochemistry on Nucleophilic Addition to a Cationic η2-Alkyne Complex, 5-C5H5)Fe(CO)2(Ph-CC-Ph)>BF4

DOI: 10.1039/c39920000451

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Journal of the Chemical Society. Chemical communications p. 451 - 453 (1992)

Update date:2022-08-24

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Authors:

Akita, Munetaka

Kakuta, Satoshi

Sugimoto, Shuichiro

Terada, Masako

Moro-oka, Yoshihiko

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Article abstract of DOI:10.1039/c39920000451

Treatment of a coordinatively saturated cationic η²-alkyne iron complex <(η⁵-C5H5)Fe(CO)2(Ph-C<*>C-Ph)>BF4 with various nucleophiles (Nu: O-, S- and N-nucleophiles) does not afford a trans-alkenyl complex but alkenic products with cis-structure, i.e. a cis-alkenyl complex, cis-(η⁵-C5H5)(CO)2Fe-C(Ph)=C(Ph)-Nu and/or a metallacycle, (η⁵-C5H5)(OC))-Nu> or (η⁵-C5H5)(OC)>.

Full text of DOI:10.1039/c39920000451

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