Journal of the Chemical Society. Chemical communications p. 451 - 453 (1992)
Update date:2022-08-24
Topics:
Akita, Munetaka
Kakuta, Satoshi
Sugimoto, Shuichiro
Terada, Masako
Moro-oka, Yoshihiko
Treatment of a coordinatively saturated cationic η2-alkyne iron complex <(η5-C5H5)Fe(CO)2(Ph-C<*>C-Ph)>BF4 with various nucleophiles (Nu: O-, S- and N-nucleophiles) does not afford a trans-alkenyl complex but alkenic products with cis-structure, i.e. a cis-alkenyl complex, cis-(η5-C5H5)(CO)2Fe-C(Ph)=C(Ph)-Nu and/or a metallacycle, (η5-C5H5)(OC)
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