Kinetic and equilibrium studies of σ-adduct formation and nucleophilic substitution in the reactions of morpholine with 1,3,5-trinitrobenzene and some phenyl aryl ethers in dimethyl sulphoxide

DOI: 10.1002/(SICI)1099-1395(199603)9:3<152::AID-POC769>3.0.CO;2-4

Source and publish data:

Journal of Physical Organic Chemistry p. 152 - 158 (1996)

Update date:2022-08-16

Topics:

Authors:

Chamberlin, Rachel A.

Crampton, Michael R.

Robotham, Ian A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/(SICI)1099-1395(199603)9:3<152::AID-POC769>3.0.CO;2-4

Reactions of morpholine in dimethyl sulphoxide at unsubstituted ring positions of 1,3,5-trinitrobenzene, and phenyl 2,4,6-trinitrophenyl ether, yield anionic σ-adducts via zwitterionic intermediates. Reactions at the 1-position of phenyl 2,4,6-trinitrophe

Full text of DOI:10.1002/(SICI)1099-1395(199603)9:3<152::AID-POC769>3.0.CO;2-4

Products guided by the article

Product name:4-(2,4-DINITROPHENYL)MORPHOLINE

Cas No:39242-76-7

R&D Labs maybe for 39242-76-7

BIOS CHEMICALS

Contact:+33-5-34012600

Address:28 ZA des Pignès
SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
Puyang Willing Chemicals Co.,Ltd.

Contact:86-393-4840366

Address:Puyang Henan China
CHEM PLUS

Contact:0027-717-456976

Address:2ND FLOOR, 325 VAUSE ROAD, OVERPORT, 4001, SOUTH AFRICA

Relevant to this article

Facilitating Ir-Catalyzed C-H Alkynylation with Electrochemistry: Anodic Oxidation-Induced Reductive Elimination

Doi:10.1021/acscatal.0c03207
(2020)
A facile synthesis of 5-acyl-6-alkyl/aryl-2,2-dimethyl-1,3-dioxin-4-ones

Doi:10.1021/jo000730p
(2000)
Thermoelectric properties of A_0.05Mo₃Sb _5.4Te_1.6 (A = Mn, Fe, Co, Ni)

Doi:10.1016/j.jallcom.2010.05.124
(2010)
Alkyne phosphonites for sequential azide-azide couplings

Doi:10.1002/anie.201302462
(2013)
Enantioselective conjugate addition of dialkylzinc to cyclic enones catalyzed by chiral binaphthyldiamine-copper(I) complexes

Doi:10.1016/j.tetlet.2007.10.061
(2007)
Doi:10.1007/BF00922062
()

Article Doi