Configurationally Fixed α-Alkoxyorganocopper Reagents: 1,4-Addition of Cyclic Enantiopure Transferable Ligands with Complete Retention of Configuration

DOI: 10.1021/jo00019a002

Source and publish data:

Journal of Organic Chemistry p. 5491 - 5493 (1991)

Update date:2022-08-16

Topics:

Authors:

Lindermann, Russell J.

Griedel, Brian D.

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Article abstract of DOI:10.1021/jo00019a002

Optically active 4-lithio-1,3-dioxanes have been converted to the corresponding TMEDA-organocopper reagents and shown to undergo conjugate addition reactions to ethyl propiolate with complete retention of configuration.

Full text of DOI:10.1021/jo00019a002

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