Journal of Chemical & Engineering Data
Article
aqueous solution, with an elongation of the alkyl chain up to
govern the thermotropic and lyotropic liquid crystalline phase
behavior and the air−water interfacial adsorption of glucose based
surfactants. Langmuir 2000, 16, 7359−7367.
C12 (B ), the value of K increases but, then, decreases.
3
An analysis of these results demonstrates that the B salt
3
(
4) Huang, X.; Han, Y.; Wang, Y.; Cao, M.; Wang, Y. Aggregation
having the C12 alkyl chain displays more effectiveness as a
petrocollecting agent, and its 5% aqueous solution may be
recommended for removing thin petroleum films off the surface
of hard waters.
properties of cationic gemini surfactants with dihydroxyethylamino
headgroups in aqueous solution. Colloids Surf., A 2008, 325, 26−32.
(5) Zhang, Zh.; Wang, H.; Shen, W. Densities, conductivities, and
aggregation numbers of aqueous solutions of quaternary ammonium
surfactants with hydroxyethyl substituents in the headgroups. J. Chem.
Eng. Data 2013, 58, 2326−2338.
4
. CONCLUSION
Ammonium-type salts containing one hydroxyethyl- and one
hydroxyisopropyl groups have been synthesized on the basis of
C , C , C , C AA, PO, and 2-chloroethanol. Colloidal-
(6) Xing, H.; Yan, P.; Zhao, K.; Xiao, J. Effect of headgroup size on
the thermodynamic properties of micellization of dodecyltrialkylam-
monium bromides. J. Chem. Eng. Data 2011, 56, 865−873.
8
9
12
16
(7) Glennie, A. R.; Mohareb, M. M.; Palepu, R. M. Thermodynamic
chemical parameters of these cationic surfactants have been
determined using the results of the applied tensiometric and
electroconductometric methods. An impact of the alkyl chain
length on the mentioned parameters has been elucidated. As in
similar ammonium-based surfactants containing the hydrox-
yethyl headgroup, in the synthesized surfactants, the Gibbs free
energy change diminishes with an increase in hydrocarbon
group length. Thermodynamic parameters indicate that
adsorption and micellization processes are of spontaneous
nature, and the obtained cationics tend initially to be adsorbed
at surface, then, to undergo micellization. In the seawater, the
and related properties of alkyl cationic surfactants based on dimethyl
and diethyl ethanol amines. J. Dispersion Sci. Technol. 2006, 27, 731−
7
38.
(8) Fan, Zh.; Tong, W.; Zheng, Q.; Lei, Q.; Fang, W. Surface activity
and micellization parameters of quaternary ammonium surfactants
containing a hydroxyethyl group. J. Chem. Eng. Data 2013, 58, 334−
342.
(9) Ren, Z. H.; Huang, J.; Luo, Y.; Zheng, Y.; Ch; Mei, P.; Yu, W.;
Ch; Lai, L.; Chang, Y. L.; Li, F. X. Effect of isopropanol on the
micellization of binary mixtures containing amino sulfonate ampho-
teric surfactant in aqueous solution: Mixing with octadecyltrimethyl
ammonium bromide. Colloids Surf., A 2016, 504, 131−138.
highest petroleum-collecting capacity is displayed by B in the
3
(10) Ren, Z. H.; Huang, J.; Luo, Y.; Zheng, Y.; Ch; Mei, P.; Yu, W.;
form of 5% wt aqueous solution. The time of this salt effect is
longer than 25 days.
Ch; Lai, L.; Chang, Y. L.; Li, F. X. Effect of isopropanol on the
micellization of binary mixture containing amino sulfonate amphoteric
surfactant in aqueous solution: Mixing with sodium dodecylbenzene
sulfonate. J. Taiwan Inst. Chem. Eng. 2016, 65, 482−487.
(11) Ren, Z. H.; Huang, J.; Zheng, Y.; Ch; Lai, L.; Hu, L. L.; Chang,
Y. L. Micellization of binary mixture of amino sulfonate amphoteric
surfactant and octylphenol polyoxyethylene ether (10) in aqueous
solution: Different electrolyte effect. J. Chem. Eng. Data 2017, 62,
ASSOCIATED CONTENT
Supporting Information
■
*
S
1
13
IR, H NMR, and C NMR spectra of B (Figures S1−
3
9
(
38−946.
S3); dependence of surface tension from natural
12) Di Michele, A.; Brinchi, L.; Di Profio, P.; Germani, R.; Savelli,
logarithm of molality for B −B at different temperatures
1
4
G.; Onori, G. Effect of head group size, temperature and counterion
specificity on cationic micelles. J. Colloid Interface Sci. 2011, 358, 160−
166.
(13) Pei, X.; You, Y.; Zhao, J.; Deng, Y.; Li, E.; Li, Z. Adsorption and
a g g r e g a t i o n o f 2 - h y d r o x y l - p r o p a n e d i y l - α , ω - b i s -
(
Tables S1−S4); dependence of specific electrical
conductivity from concentration of B −B salts at
different temperatures (Tables S5−S8) (PDF)
4
(
dimethyldodecylammonium bromide) in aqueous solution: Effect of
AUTHOR INFORMATION
Corresponding Author
ORCID
Funding
The publication was supported by Institute of Petrochemical
Processes of National Academy of Sciences of Azerbaijan and
the Ministry of Education and Science of the Russian
Federation (the Agreement number 02.a03.21.0008).
■
intermolecular hydrogen-bonding. J. Colloid Interface Sci. 2010, 351,
4
57−465.
(14) Liu, W.-Sh.; Wang, Ch.-H.; Sun, J.-F.; Hou, G.-G.; Wang, Y.-P.;
Qu, R.-J. Synthesis, Characterization and antibacterial properties of
dihydroxy quaternary ammonium salts with long chain alkyl bromides.
Chem. Biol. Drug Des. 2015, 85, 91−97.
(15) Chatterjee, A.; Maiti, S.; Sanyal, S. K.; Moulik, S. P. Micellization
and related behaviors of N-cetyl-N-ethanolyl-N,N-dimethyl and N-
cetyl-N,N-diethanolyl-N-methyl ammonium bromide. Langmuir 2002,
18, 2998−3004.
(16) Tong, W.; Zheng, Q.; Shao, Sh.; Lei, Q.; Fang, W. Critical
micellar concentrations of quaternary ammonium surfactants with
hydroxyethyl substituents on head groups determined by isothermal
titration calorimetry. J. Chem. Eng. Data 2010, 55, 3766−3771.
Notes
The authors declare no competing financial interest.
(17) Song, B.; Shang, Sh.; Song, Zh. Solution behavior and solid
phase transitions of quaternary ammonium surfactants with head
groups decorated by hydroxyl groups. J. Colloid Interface Sci. 2012, 382,
53−60.
(18) Asadov, Z. H.; Rahimov, R. A.; Mammadova, Kh.A.; Ahmadova,
G. A.; Ahmadbayova, S. F. Synthesis and colloidal-chemical properties
of surfactants based on alkyl amines and propylene oxide. Tenside,
Surfactants, Deterg. 2015, 52, 287−293.
(19) Sun, Y.; Wang, Ch.; Wang, W.; Yang, X.; Di Serio, M.; Zhi, L.
Micellar properties for propoxylated surfactants in water/alcohol
solvent mixtures and their antibacterial and polyester fabric antistatic
performances. J. Surfactants Deterg. 2016, 19, 543−552.
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J. Chem. Eng. Data XXXX, XXX, XXX−XXX