Journal of the Chemical Society. Chemical communications p. 1363 - 1364 (1994)
Update date:2022-08-25
Topics:
Hosken, Gladys D.
Hancock, Robert D.
Synthesis of 3,7-bis(2-pyridylmethyl)-3,7-diazabicyclo<3.3.1>nonane DPB, with very rigid nitrogen-bridge reinforcement gives an adamantane-like structure once a metal ion is coordinated to DPB, and shows how remarkable stability enhancement and selectivity for metal ions on the basis of size can be achieved in non-macrocyclic ligands.
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