RSC Advances p. 11727 - 11736 (2020)
Update date:2022-08-15
Topics:
Beltramini, Jorge N.
Hayami, Shinya
Hirano, Yui
Karim, Mohammad Razaul
Kim, Yang
Mori, Atsushi
Nakamura, Manami
Nakamura, Masaaki
Hybrids of reduced graphene oxide (rGO) and metal/metal oxide (Pt, NiO/Ni(OH)2, CoO, Fe3O4) nano particle were prepared by reduction of graphene oxide (GO) and metal ion (Pt2+, Ni2+, Co2+, Fe2+) hybrids. The M-rGO hybrids (M = Pt, Ni-, Co and Fe) were justified for the transformation of glucose to 5-hydroxymethylfurfural (5-HMF). High glucose → 5-HMF conversion was yielded depending on the nature of the M-rGO catalyst. The Ni-rGO showed the highest 5-HMF yield. The conversion reaction tuned to the optimized state under a microwave-assisted reaction accomplished by using Ni-rGO. In such case, the conversion rate was 99% with a 5-HMF yield of 75%. In order to improve both the conversion and yield, NiGO-FD was prepared by a freeze-dry method. The NiGO-FD remarkably showed the highest conversion of 99% and 5-HMF yield of 95%. Beside the biomass transformation process, the physico-chemical strategy employed herein for multiplying the catalytic efficiency might be justified for catalyzing similar reactions.
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Doi:10.1007/s11164-012-0506-0
(2012)Doi:10.1111/j.1551-2916.2010.03719.x
(2010)Doi:10.1063/1.432110
(1976)Doi:10.1039/c5ra11765h
(2015)Doi:10.1080/00397919108021576
(1991)Doi:10.1002/cjoc.201400886
(2015)