Photochemical Selective Fluorination of Organic Molecules Using Mercury (II) Fluoride

DOI: 10.1016/S0022-1139(00)80299-7

Source and publish data:

Journal of Fluorine Chemistry p. 291 - 294 (1991)

Update date:2022-08-11

Topics:

Authors:

Habibi, Mohammed H.

Mallouk, Thomas E.

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Article abstract of DOI:10.1016/S0022-1139(00)80299-7

Organic compounds, such as triphenylacetic acid, triphenyl ethylene, and triethyl phosphite can be selectively fluorinated in dimethylsulfoxide/HgF2 solutions under UV-visible illumination.Product yields, determined by 19F-NMR, are essentially quantitative for the compounds studied, and in some cases a single fluorinated product is formed.

Full text of DOI:10.1016/S0022-1139(00)80299-7

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