A Short and Efficient Synthetic Method for the Corticosteroid Side-Chain from 17-Keto Steroids

DOI: 10.1246/cl.1990.1705

Source and publish data:

Chemistry Letters p. 1705 - 1708 (1990)

Update date:2022-08-11

Topics:

Authors:

Kataoka, Hideaki

Watanabe, Kiyoshi

Miyazaki, Ken-ichi

Tahara, Shin-ichiro

Ogu, Ken-ichi

et al. et al.

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Article abstract of DOI:10.1246/cl.1990.1705

21-Acyloxy-16(17)-ene-20-keto steroids were synthesized from 17-keto steroids in 4 steps using palladium(II)-catalyzed oxidative rearrangement of propargyl esters as a key reaction.

Full text of DOI:10.1246/cl.1990.1705

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