Selenoimidoylation of alcohols with selenium and isocyanides and its application to the synthesis of selenium-containing heterocycles

DOI: 10.1021/jo0496704

Source and publish data:

Journal of Organic Chemistry p. 4845 - 4848 (2004)

Update date:2022-08-25

Topics:

Authors:

Asanuma, Yoshiaki

Fujiwara, Shin-Ichi

Shin-Ike, Tsutomu

Kambe, Nobuaki

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Article abstract of DOI:10.1021/jo0496704

The reaction of alcohols with selenium and isocyanides in the presence of DBU gave oxyimidoylselenoates 6. Trapping of 6 with BuI resulted in high-yield formation of selenocarbonimidates 4. When alk-2-yn-1-ols 9 were allowed to react with selenium and iso

Full text of DOI:10.1021/jo0496704

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