A concise enantiospecific synthesis of nuphar piperidine alkaloids: Total synthesis of (-)-anhydronupharamine, (-)-nupharamine, (-)-nuphenine and (+)-3-epinupharamine

DOI: 10.1039/c39940000499

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 499 - 500 (1994)

Update date:2022-08-11

Topics:

Authors:

Honda Honda

Ishikawa

Yamane -i.

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Article abstract of DOI:10.1039/c39940000499

Enantiospecific syntheses of (-)-anhydronupharamine, (-)-nupharamine, (-)-nuphenine, and (+)-3-epinupharamine are achieved starting from (-)- or (+)-carvone as chiral sources, in which a regioselective reductive fragmentation of the cyclopentane derivatives and an intramolecular aza-Wittig reaction were involved as key reactions.

Full text of DOI:10.1039/c39940000499

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Product name:(2S)-6β-(3-Furanyl)-3α-methyl-2β-(3-methyl-2-butenyl)piperidine

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