Chemistry Letters p. 31 - 34 (1982)
Update date:2022-08-17
Topics:
Kondo, Hiroki
Yoshinaga, Hiroyuki
Morita, Kanzi
Sunamoto, Junzo
The cyclization of pyridoxal Schiff base of histidine or histamine is prohibited by metal ions such as Cu2+ and Zn2+.On the basis of a similar extent of metal inhibition for histidine and histamine, it is concluded that an identical Schiff base complex with the imidazole group coordinating to the metal is responsible for the inertness of both substrates.
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