STRUCTURE OF THE METAL SCHIFF BASE COMPLEX OF PYRIDOXAL AND HISTIDINE IN SOLUTION

DOI: 10.1246/cl.1982.31

Source and publish data:

Chemistry Letters p. 31 - 34 (1982)

Update date:2022-08-17

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Authors:

Kondo, Hiroki

Yoshinaga, Hiroyuki

Morita, Kanzi

Sunamoto, Junzo

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Article abstract of DOI:10.1246/cl.1982.31

The cyclization of pyridoxal Schiff base of histidine or histamine is prohibited by metal ions such as Cu²⁺ and Zn²⁺.On the basis of a similar extent of metal inhibition for histidine and histamine, it is concluded that an identical Schiff base complex with the imidazole group coordinating to the metal is responsible for the inertness of both substrates.

Full text of DOI:10.1246/cl.1982.31

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