Chemistry Letters p. 1529 - 1532 (1981)
Update date:2022-08-29
Topics:
Suzuki, Keisuke
Mukaiyama, Teruaki
Yuki, Yoichi
In the presence of zinc halide, 2-furyllithium reacts with 2,3-O-isopropylidene-D-glyceraldehyde in a highly stereoselective manner to give the chiral and stereo-defined alcohol, 2,2-dimethyl-4-(2-furyl)hydroxymethyl-1,3-dioxolane, which is further elaborated to afford D-ribulose in three steps.
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