Chemistry Letters p. 1967 - 1970 (1982)
Update date:2022-08-17
Topics:
Hamanoue, Kumao
Yokoyama, Kazuo
Miyake, Takao
Kasuya, Toshihiro
Nakayama, Toshihiro
Teranishi, Hiroshi
Irradation of 1,5-dichloroanthraquionone (1,5-DCAQ) with 366 nm light in ethanol gives anthrahydroquinone (AQH2) as a final product.This is interpreted interms of the following cosecutive reactions; 1,5-DCAQ --hν--> 1,5-dichloroanthrahydroquinone --hν--> 1-chloroanthraquinone --hν--> 1-chloroanthrahydroquinone --hν--> anthraquinone --hν--> AQH2.Similar reactions were also observed for other α-chloroanthraquinones.
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