Reaction rate constants of HO2 + O3 in the temperature range 233-400 K

Article abstract of DOI:10.1063/1.454169

The reaction rate constants of HO2 + O3 were measured as a function of temperature.HO2 was produced by the reaction sequence: Cl + CH3OH -> CH2OH + HCl and CH2OH + O2 -> HO2 + CH2O.HO2 was detected by the OH (A-X) fluorescence produced by photoexcitation of HO2 at 147 nm.The reaction rate constants are represented by k(T) = (1.8 +/- 0.6)*10^-14 exp < - (680 +/- 148)/T >cm³/s in 253-400 K, and are nearly a constant of (1.3 +/- 0.3)*10^-15 cm³/s in 233-253 K.

Full text of DOI:10.1063/1.454169

Reaction rate constants of HO2+O3 in the temperature range 233–400 K
Xiuyan Wang, Masako Suto, and L. C. Lee
Citation: The Journal of Chemical Physics 88, 896 (1988); doi: 10.1063/1.454169
View online: http://dx.doi.org/10.1063/1.454169
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/88/2?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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