Synthesis and reactivity of functional 1-methyl-silacyclopentenes

DOI: 10.1016/0022-328X(94)84048-2

Source and publish data:

Journal of Organometallic Chemistry p. 71 - 82 (1994)

Update date:2022-08-29

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Authors:

Heinicke, J.

Gehrhus, B.

Meinel, S.

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Article abstract of DOI:10.1016/0022-328X(94)84048-2

The silylenes MeSiCl, MeSiOMe and MeSiNMe2 can be thermally generated from disilanes and trapped by butadiene, isoprene and 2,3-dimethylbutadiene to give functionally-substituted silacyclopentenes.Some examples of cycloadditions to heterodienes are includ

Full text of DOI:10.1016/0022-328X(94)84048-2

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