REGIOSELECTIVITY OF HYDRIDE ADDITION TO 5-C5H5)Fe(Ph2PCH2CH2PPh2)CO>PF6 AND REARRANGEMENT OF (η5-C5H5)Fe(Ph2PCH2CH2PPh2)(CO)H TO (η4-C5H6)Fe(Ph2PCH2CH2PPh2)CO

DOI: 10.1016/S0022-328X(00)98661-3

Source and publish data:

Journal of Organometallic Chemistry p. C16 - C18 (1983)

Update date:2022-07-29

Topics:

Authors:

Davies, Stephen G.

Hibberd, John

Simpson, Stephen J.

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Article abstract of DOI:10.1016/S0022-328X(00)98661-3

In tetrahydrofuran ar reflux <(η⁵-C5H5)Fe(Ph2PCH2CH2PPh2)CO>PF6 undergoes hydride attack both on CO and exo on the cyclopentadienyl ligand, whereas at -78 deg C hydride addition occurs regioselectivity at CO give (η⁵-C5H5)FePh2PCH2CH

Full text of DOI:10.1016/S0022-328X(00)98661-3

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