Journal of Organometallic Chemistry p. 1 - 6 (1992)
Update date:2022-08-11
Topics:
Schoufs, H.J.M.
Maercker, A.
Brandsma, L.
Reaction of 1,4-thiatellurin and some of its alkyl derivatives with n-butyllithium in tetrahydrofuran gives Z,Z-2,2'-dilithiodivinyl sulfide or alkyl derivatives and dibutyl telluride.With lithium diisopropylamide in tetrahydrofuran, in the case of 3,5'-dialkyl-1,4-thiatellurins, deprotonation with concomitant ring opening is the main reaction.
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