Journal of Physical Chemistry p. 1885 - 1888 (1984)
Update date:2022-08-29
Topics:
Lovell, Michael W.
Vogt, Brian S.
Schulman, Stephen G.
The protonation of several monocationic bases in perchloric acid was studied with UV-visible absorption spectroscopy.The H+ scale in perchloric acid was established by using primary amine cationic bases as indicators.It was found that the H+ scale in perchloric acid is more negative than in sulfuric acid.The acid-dissociation constants for compounds studied in both acids were found to be in reasonably good agreement with each other.
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