Chemistry Letters p. 255 - 256 (1980)
Update date:2022-08-16
Topics:
Mukaiyama, Teruaki
Suzuki, Keisuke
Various optically active acetylenic alcohols (40-80percent e.e.) were obtained by enantioface-differentiating addition of lithium trimethylsilylacetylide to aliphatic aldehydes utilizing (2S, 2'S)-2-hydroxymethyl-1-<(1-methylpyrrolidin-2-yl)methyl>pyrrolidine as achiral ligand.Optically active (R)-1-trimethylsilyl-1-undecyn-3-ol 80percente.e.) was transformed into optically active 5-octyl-2(5H)-furanone in good yield.
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Doi:10.1016/S0957-4166(99)00063-4
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(1987)
