Synthesis of Dienoic Acids and Esters by Cationic Palladium Complex Catalyzed Carbonylation of Alkynols and Alkynediols

DOI: 10.1021/jo00077a008

Source and publish data:

Journal of Organic Chemistry p. 6956 - 6957 (1993)

Update date:2022-08-10

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Authors:

Huh, Keun-Tae

Orita, Akihiro

Alper, Howard

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Article abstract of DOI:10.1021/jo00077a008

The cationic palladium(II) aquo hydride, trans-(Cy3P)2Pd(H)(H2O)(+)BF4(-), is an excellent catalyst for the carbonylation of alkynols to dienoic acids and esters and of alkynediols to cross-conjugated diesters.

Full text of DOI:10.1021/jo00077a008

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