Bulletin of the Chemical Society of Japan p. 1471 - 1472 (1980)
Update date:2022-08-16
Topics:
Miyaura, Norio
Yano, Takashi
Suzuki, Akira
The reactions between copper(I) 1-alkenyltrimethylborates ( readily obtainable from 2-(1-alkenyl)-1,3,2-benzodioxaboroles and methyllithium) and allylic bromides or 2-propynyl bromide were found to give corresponding coupling products.These reactions provide new synthetic routes to 1,4-alkadienes or 1,2,7-alkatrien-5-ynes.
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