Stereoselective synthesis of 11Z-retinal by use of tricarbonyliron complex

DOI: 10.1016/0960-894X(96)00369-1

Source and publish data:

Bioorganic and Medicinal Chemistry Letters p. 2049 - 2052 (1996)

Update date:2022-08-12

Topics:

Authors:

Wada, Akimori

Tanaka, Yukiko

Fujioka, Naoko

Ito, Masayoshi

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Article abstract of DOI:10.1016/0960-894X(96)00369-1

Peterson reaction of 7E,9E-β-ionylideneacetaldehyde-tricarbonyliron complex with ethyl trimethylsilyl acetate afforded Z-olefin in high stereoselectivity, which was converted to the corresponding 11Z-retinal in excellent yield.

Full text of DOI:10.1016/0960-894X(96)00369-1

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