Asymmetric Michael reaction. Deracemization of enolate by chiral crown ether

DOI: 10.1016/0040-4039(95)01150-G

Source and publish data:

Tetrahedron Letters p. 5951 - 5954 (1995)

Update date:2022-08-30

Topics:

Authors:

Toke, Laszlo

Fenichel, Laszlo

Albert, Melinda

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Article abstract of DOI:10.1016/0040-4039(95)01150-G

Crown ethers anellated to sugar units have been used to catalyse the enantioselective carbon-carbon bond forming reaction of methyl phenylacetate with methyl acrylate. A novel CH-acid deracemization has also been discovered in this study.

Full text of DOI:10.1016/0040-4039(95)01150-G

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