Asymmetric Michael reaction. Deracemization of enolate by chiral crown ether

DOI: 10.1016/0040-4039(95)01150-G

Source and publish data:

Tetrahedron Letters p. 5951 - 5954 (1995)

Update date:2022-08-30

Topics:

Authors:

Toke, Laszlo

Fenichel, Laszlo

Albert, Melinda

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)01150-G

Crown ethers anellated to sugar units have been used to catalyse the enantioselective carbon-carbon bond forming reaction of methyl phenylacetate with methyl acrylate. A novel CH-acid deracemization has also been discovered in this study.

Full text of DOI:10.1016/0040-4039(95)01150-G

Products guided by the article

Product name:Pentanedioic acid, 2-phenyl-, dimethyl ester, (R)-

Cas No:56523-52-5

R&D Labs maybe for 56523-52-5

NINGBO YINZHOU PRECISE COLOR CO.,LTD.

Contact:86-574-88139809 86-574-83033159

Address:Qiming Road,Yinzhou,Ningbo,China
Chongqing Shuangfeng Chemical Co.,Ltd

Contact:+86-23-49850156

Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Xiamen Kaijia Imp & Exp Co., Ltd.

Contact:86-592-5101177

Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
Hubei Onward Bio-Development Co., Ltd.

Contact:+86-718-8417012

Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Nanjing yieldpharma co.ltd

Contact:13813902930 025-52714267

Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China

Relevant to this article

Doi:10.1021/ja01278a010
(1938)
Constituents of Clausena excavata. Isolation and structural elucidation of seven new carbazole alkaloids and a new coumarin

Doi:10.1248/cpb.44.2231
(1996)
Copper(i) pyrimidine-2-thiolate cluster-based polymers as bifunctional visible-light-photocatalysts for chemoselective transfer hydrogenation of α,β-unsaturated carbonyls

Doi:10.1039/d1ra01102b
(2021)
Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Doi:10.1039/b412736f
(2005)
EFFECT OF SOLVENT ON THE ESTERIFICATION BETWEEN 1,1,1-TRIFLUOROCHLORETHANE AND AKALINE ACETATE

Doi:10.1016/S0022-1139(00)83412-0
(1985)
Desulfurization of 2-thioxo-1,2,3,4-tetrahydropyrimidin-4-ones with oxiranes and 2-haloacetonitriles

Doi:10.1007/s11178-005-0211-1
(2005)

Article Doi