Bulletin of the Chemical Society of Japan p. 511 - 514 (1986)
Update date:2022-08-11
Topics:
Mori, Akira
Isayama, Yasutoshi
Takeshita, Hitoshi
Unlike the benzenoid equivalent, p-methoxyphenol, the cerium(IV) ammonium nitrate (CAN)-oxidation of 5-hydroxy-2-methoxytropone gave C-C coupling products.On the other hand, either by thallium(III) nitrate (TTN) or CAN at 50 deg C, 5-hydroxytropolone, a free tropolone, gave 3-methoxy-p-tropoquinone together with p-tropoquinone and 8-oxabicyclo<3.2.1>octenone derivatives, but no dimeric product.
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(1986)
