Highly stereoselective synthesis of β-lactams by condensation of the titanium enolate of a chiral 2-pyridylthioester with chiral imines

DOI: 10.1016/0040-4020(95)00574-R

Source and publish data:

Tetrahedron p. 10025 - 10032 (1995)

Update date:2022-08-11

Topics:

Authors:

Annunziata, Rita

Benaglia, Maurizio

Chiovato, Alessandro

Cinquini, Mauro

Cozzi, Franco

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Article abstract of DOI:10.1016/0040-4020(95)00574-R

The reaction of the titanium enolate of a 2-pyridylthioester derived from (R)-3-hydroxybutyric acid with chiral imines affords 3,3'-anti-3,4-trans configurated β-lactams in a highly selective fashion. The methodology has been applied to the synthesis of a

Full text of DOI:10.1016/0040-4020(95)00574-R

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