Journal of Organic Chemistry p. 1843 - 1845 (1984)
Update date:2022-08-11
Topics:
Nelsen, Stephen F.
Teasley, Mark F.
Kapp, Daniel L.
Wilson, R. Marshall
Bicyclic bis(tertiary) peroxides 2 and 3 give long-lived radical cations at room temperature, despite their high oxidation potentials (Edeg C'=2.18 and 2.29 V vs.SCE,recpectively).The ESR spectra of the radical cations are reported, and the reason for oxidation being so much harder for peroxides than for hydrazines is discussed.
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