Corannulene synthesis via the pyrolysis of silyl vinyl ethers

DOI: 10.1016/0040-4039(96)00588-6

Source and publish data:

Tetrahedron Letters p. 3437 - 3440 (1996)

Update date:2022-08-11

Topics:

Authors:

Liu, Charlie Z.

Rabideau, Peter W.

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Article abstract of DOI:10.1016/0040-4039(96)00588-6

The bis(trimethylsilyl enol ether) derived from 7,10-diacetylfluoranthene undergoes pyrolysis to afford corannulene. This is important in cases where the usual precursor, the bis(chlorovinyl) derivative, is not accessible from the diketone.

Full text of DOI:10.1016/0040-4039(96)00588-6

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