
Journal of the Less-Common Metals p. 107 - 112 (1988)
Update date:2022-08-11
Topics:
Paljevic M.
The oxidation of ZrAl in dry oxygen in the temperature range 800 - 1100 K follows a parabolic rate law. An activation energy of 86. 4 kJ mol** minus **1 was estimated. During the oxidation, aluminum diffuses from the oxide layer to the ZrAl bulk, thus forming a ZrAl//2 phase very close to the oxide-alloy interface. The excess zirconium is therefore selectively oxidized, yielding tetragonal mainly and monoclinic ZrO//2 containing no Al//2O//3.
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Doi:10.1007/BF00563606
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(1979)