Hydrolysis of Acetonitrile, Catalyzed by Octaacetatotetraplatinum(II). - High Reactivity of Coordination Sites Trans to the Pt-Pt Bond -

DOI: 10.1246/bcsj.67.3116

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3116 - 3118 (1994)

Update date:2022-08-28

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Authors:

Yamaguchi, Tadashi

Adachi, Hisako

Ito, Tasuku

Sasaki, Yoichi

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Article abstract of DOI:10.1246/bcsj.67.3116

The platinum(II) cluster, , catalyzes the hydrolysis of acetonitrile to acetamide in acetonitrile-water mixtures.Typical turnover number was 104 mol h^-1 at 80 deg C.The catalyst was slowly deactivated by the accumulation of the less active acetamide-substituted species, as well as by its decomposition.

Full text of DOI:10.1246/bcsj.67.3116

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