Russian Journal of General Chemistry p. 461 - 467 (2005)
Update date:2022-08-28
Topics:
Kosareva
Klyueva
Lomova
Suslova
The acid-induced dissociation of copper(II) porphyrin complexes with a high degree of meso- and β-substitution in the ligand was studied. The copper(II) complexes with octaethylporphyrins containing 0, 1, 2, 3, and 4 meso-phenyl substituents were ranked with respect to the stability. Octaβ-alkyl and unsymmetrical meso-phenyl substitution affects not only the quantitative characteristics of dissociation of the complexes but also the kinetic relationships of the process. 2005 Pleiades Publishing, Inc.
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