THE RELEVANCE OF ESTER EXCHANGE IN OXALACETIC ESTERS TO THE DECARBONMONOXYLATION REACTION

DOI: 10.1016/S0040-4039(00)98685-4

Source and publish data:

Tetrahedron Letters p. 3911 - 3914 (1985)

Update date:2022-08-25

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Authors:

Fitzhugh, Anthony L.

Strauss, Richard S.

Brewer, Elizabeth N.

Glassman, Steven D.

Jones, Maitland

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Article abstract of DOI:10.1016/S0040-4039(00)98685-4

Oxalacetic esters undergo ester exchange at 120 deg C, at which temperature loss of CO does not occur.A new mechanism is proposed for the decarbonmonoxylation reaction.

Full text of DOI:10.1016/S0040-4039(00)98685-4

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