Angewandte Chemie - International Edition p. 9116 - 9119 (2011)
Update date:2022-08-30
Topics:
Snell, Robert H.
Woodward, Robert L.
Willis, Michael C.
The power of palladium: The total synthesis of the alkaloid hodgkinsine B has been achieved with just six isolated intermediates and only four chromatographic operations. The route involves a palladium-catalyzed enantioselective desymmetrizing N-allylation of meso- chimonanthine to establish the absolute configuration and elaboration of the desymmetrized core by a diastereoselective palladium-catalyzed α-oxindole arylation. Copyright
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