N,N-Dimethoxyamine; a New Methylating, Aminating, and Epiminating Reagent

DOI: 10.1039/c39900000261

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 261 - 262 (1990)

Update date:2022-08-24

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Authors:

Rudchenko, Vladimir F.

Ignatov, Sergei M.

Kostyanovsky, Remir G.

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Article abstract of DOI:10.1039/c39900000261

Electrophilically catalysed cleavage of the N-O bond of N,N-dimethoxyamine results in the formation of singlet N-methoxynitrenium ion, which aminates soft nucleophiles, methylates hard ones, and epiminates alkenes.

Full text of DOI:10.1039/c39900000261

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