
Synthesis p. 766 - 768 (1986)
Update date:2022-08-17
Topics:
Miyakoshi, Tetsuo
4-Oxoalkanals(γ-Ketoaldehydes), which are important intermediates for the syntheses of jasmonoids and pheromones, are prepared from the Michael reaction of nitroalkanes with acrolein catalyzed by tributylphosphine, followed by an electrochemical oxidative Nef reaction of the resultant 4-nitroalkanal ethylene acetals.
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