3 + 2 Cycloaddition via a Diels-Alder/retro-Diels-Alder sequence: Tandem cyclopentadienyl annulation of a 1,5-cyclooctadiyne synthetic equivalent

DOI: 10.1016/0040-4039(96)00384-X

Source and publish data:

Tetrahedron Letters p. 2517 - 2520 (1996)

Update date:2022-08-29

Topics:

Authors:

Davila, Alfonso

Ramezanian, Merrikh S.

Fronczek, Frank R.

McLaughlin, Mark L.

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Article abstract of DOI:10.1016/0040-4039(96)00384-X

A novel method of synthesizing a 1,2-bis(ethano) bridged bis(cyclopentadienyl) compound, 6,13-diisopropylidenetricyclo[9.3.0(1,11).0(4,8]tetradeca-1(14),4,7,11 -tetraene, 5, via a tandem Diels-Alder/retro-Diels-Alder sequence using a 1,5-cyclooctadiyne synthetic equivalent and 6,6-dimethylfulvene is reported.

Full text of DOI:10.1016/0040-4039(96)00384-X

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