404
XU, BORING, AND HILL
preparationsofH [AlW
O
]and Na [AlW O ](see reference (27a)), 15. Representative recent papers on supported POMs as catalysts:
5
12 40 12 40
5
Dr. Fred Strobel of the Emory University Mass Spectrometry Center for
mass spectrometric measurements, Dr. Robert Apkarian of the Emory
University Integrated Scanning Electron Microscopy and Microanalytical
Facility for the SEM pictures, Huadong Zeng for NMR experiments, and
William Bell of TDA Research for the N2 BET surface area measurements.
(a) Gall, R. D., Hill, C. L., and Walker, J. E., Chem. Mater. 8, 2523–
2527 (1996); (b) Gall, R. D., Hill, C. L., and Walker, J. E., J. Catal.
159, 473–478 (1996); (c) Izumi, Y., and Urabe, K., Chem. Lett., 663–
666 (1981); (d) Neumann, R., and Levin, M., J. Org. Chem. 56, 5707–
5710 (1991); (e) Fujibayashi, S., Nakayama, K., Nishiyama, Y., and
Ishii, Y., Chem. Lett., 1345–1348 (1994); (f) Dupont, P., Vedrine, J. C.,
Paumard, E., Hecquet, G., and Lefebvre, F., Appl. Catal. A—General
129, 217–227 (1995); (g) POM-containing catalytically active den-
drimers: Zeng, H., Newkome, G., Hill, C. L., Angew. Chem. Intern.
Ed. Engl. 39, 1772–1774 (2000).
REFERENCES
1. Fukumoto, K., Onoda, S., Sugiura, M., Horii, M., and Hayashi, H.,
United States patent 5,603,927 (1997).
2. Seki, K., Fiber Technol. (Jap.) 49, 448 (1996).
16. Mori, H.-O., Mizuno, N., and Misono, M., J. Catal. 131, 133–142
(1991).
3. Dimotakis, E. D., Cal, M. P., and Economy, J., Environ. Sci. Technol. 17. (a) Harrup, M. K., and Hill, C. L., Inorg. Chem. 33, 5448–55 (1994);
29, 1876–1880 (1995).
(b) Harrup, M. K., and Hill, C. L., J. Mol. Catal. A: Chem. 106, 57–66.
4. Misaki, Y., and Seki, K., Japan patent 08074131 (1996).
5. Yoshikawa, S., and Shimamura, S., Japan patent 01236056 (1989).
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7. Riley, D. P., Inorg. Chem. 22, 1965–1967 (1983).
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(1996).
18. Hill, C. L., and Gall, R. D., J. Mol. Catal. A: Chem. 114, 103–111
(1996).
19. Kozhevnikov, I. V., Chem. Rev. 98, 171–198 (1998).
20. Gall, R. D., Hill, C. L., and Walker, J. E., Chem. Mater. 8, 2523–2527
(1996).
9. Sheldon, R. A., and Kochi, J. K., in “Metal-Catalyzed Oxidations of
21. Gall, R. D., Hill, C. L., and Walker, J. E., J. Catal. 159, 473–478 (1996).
Organic Compounds,” Chaps. 2 and 3, Academic Press, New York, 22. Neumann, R., and Levin, M., J. Org. Chem. 56, 5707–5710 (1991).
1981.
23. Representative patents on POMs in applications of pigments, dyes
and inks: (a) Clarke, R. A., United States patent 3,387,916 (1968);
(b) Ludwig, T. E., and Heights, C., United States patent 4,444,592
(1984); (c) Forschirm, A. S., Hiawatha, L., Wissburn, K. F., and Hills,
S., United States patent 3,925,006 (1975); (d) Kakinuma, K., Nose,
K., and Goto, Y., Japan patent 50136488 (1976); (e) Jackson, C. E. J.,
Kasowski, R. V., and Lee, K.-S., WO 9420565 (1994).
10. Representative recent papers on photocatalysis of related reactions:
(a) Wada, K., Yoshida, K., Watanabe, Y., and Mitsudo, T.-A., J. Chem.
Soc., Faraday Trans. 92, 685-91 (1996); (b) Kudo, A., and Sakata, T.,
Chem. Lett., 2381-4 (1992); (c) Shul’pin, G. B., Nizova, G. V., and
Kats, M. M., Neftekhimiya 31, 658-65 (1991); (d) Shul’pin, G. B.,
and Kats, M. M., Neftekhimiya 31, 648-57 (1991); (e) Nisova, G. V.,
and Shul’pin, G. B., Izv. Akad. Nauk SSSR, Ser. Khim., 2393 (1989); 24. Mizuno, N., Watanabe, T., Mori, H., and Misono, M., J. Catal. 123,
(f) Papaconstantinou, E., Chem. Soc. Rev. 18, 1–31 (1989); (g) Hill, 157–163 (1990).
C. L., and Prosser-McCartha, C. M., Catal. Met. Complexes 14, 307–330 25. Akio, F., Yu, F., Inoue, M., Maki, M., and Kaneko, Y., Japan patent
(1993);(h) Sattari, D., and Hill, C. L., J. Am. Chem. Soc. 115, 4649–4657 0435716 [92,30,857] (1992).
(1993); (i) Frisen, D. A., Gibson, D. B., and Langford, C. H., Chem. 26. Pettersson, L., Andersson, I., and Selling, A., Inorg. Chem. 33, 982–
Commun., 543–544 (1998); (j) Hill, C. L., Synlett. 2, 127–132 (1995);
(k) Mylonas, A., Papaconstantinou, E., and Roussis, V., Polyhedron
15, 3211–3217 (1996).
993 (1994).
27. (a) Weinstock, I. A., Cowan, J. J., Barbuzzi, E. M. G., Zeng, H., and
Hill, C. L., J. Am. Chem. Soc. 121, 4608–4617 (1999); (b) Mair, J. A.,
and Waugh, J. L. T., J. Chem. Soc. 1950, 2372–2376 (1950); (c) Wamsley,
F., J. Chem. Education 69, 936–939 (1992); (d) CoCl2 4H2O (1.07 g,
5.1 mmol) was dissolved in water (800 mL). To this solution, solid
K9SiVW10O39 14H2O (12.6 g, mmol) was added slowly in portions
while keeping the pH less than 7 with 3 M HCl. After addition of
the solid, the pH of the cloudy orange solution was adjusted to 5.2
with 3 M HCl to give a red-orange solution. After one h, 100 g of
solid KCl was added resulting a brown precipitate was collected by
filtration and washed with cold water, EtOH, and Et2O; (e) 2.0 g of
K7SiVCo(H2O)W10O39 13H2O was dissolved in a minimal amount of
H2O. This solution was stirred by syringe and to it was added an excess
amount (>5 equivalents) of hydrazine. KCl (3.0 g) was added and after
10 min of stirring at room temperature, the solution was chilled at 0 C
overnight. The solution was then filtered to yield 1.5 g of a dark red
solid.
28. Hill, C. L., and Prosser-McCartha, C. M., Coord. Chem. Rev. 143, 407–
455 (1995).
29. (a) Neumann, R., Prog. Inorg. Chem. 47, 317–370 (1998); (b) Khenkin,
A. M., Rosenberger, A., and Neumann, R., J. Catal. 182, 82–91
(1999).
30. Neumann, R., and Levin, M., J. Am. Chem. Soc. 114, 7278–7286
(1992).
31. Kholdeeva, O. A., Grigoriev, V. A., Maksimov, G. M., and Zamaraev,
K. I., Top. Catal. 3, 313–325 (1996).
11. Fortunato, P., Reller, A., and Oswald, H. R., Solid State Ionics 101–103,
85–89 (1997).
12. Representative recent papers on aerobic oxidations in the presence
of aldehyde: (a) Neumann, R., Prog. Inorg. Chem. 47, 317–370 (1998);
(b) Mori, H.-O., Mizuno, N., and Misono, M., J. Catal. 131, 133–
142 (1991); (c) Yan, Y.-Y., Dong, L.-M., Guo, J.-P., Huang, M.-Y.,
and Jiang, Y.-Y., J. Macromol. Sci., Pure Appl. Chem. A 34, 1097–
1104 (1997); (d) Komiya, N., Naota, T., Oda, Y., and Murahashi, S.-I.,
J. Mol. Catal. A: Chem. 117, 21–37 (1997); (e) Mandal, A. K., Khanna,
V., and Iqbal, J., Tetrahedron Lett. 37, 3769–3772 (1996); (f) Murahashi,
S., Oda, Y., Naota, T., and Komiya, N., J. Chem. Soc., Chem. Commun.,
139-40 (1993); (g) Murahashi, S., Oda, Y., and Naota, T., Tetrahedron
Lett. 33, 7557-60 (1992); (h) Murahashi, S., Oda, Y., and Naota, T.,
J. Am. Chem. Soc. 114, 7913-14 (1992); (i) Yamada, T., Takahashi, K.,
Kato, K., Takai, T., Inoki, S., and Mukaiyama, T., Chem. Lett., 641-4
(1991).
13. General reviews of POMs: (a) Pope, M. T., and Mu¨ller, A., Angew.
Chem., Intl. Ed. Engl. 30, 34–48 (1991); (b) Hill, C. L. (Ed.), Special
issue on polyoxometalates, Chem. Rev. 98, 1-387 (1998); (c) Review of
biological properties: Rhule, J. T., Hill, C. L., Judd, D. A., and Schinazi,
R. F., Chem. Rev. 98, 327–357 (1998).
14. Recent reviews on POMs in catalysis: (a) Hill, C. L., and Prosser-
McCartha, C. M., Coord. Chem. Rev. 143, 407–455 (1995); (b)
Okuhara, T., Mizuno, N., and Misono, M., Adv. Catal. 41, 113–252
(1996);(c) Kozhevnikov, I., Chem. Rev. 98, 171–198(1998);(d) Mizuno,
N., and Misono, M., Chem. Rev. 98, 199–218 (1998); (e) Neumann, R.,
Prog. Inorg. Chem. 47, 317–370 (1998).
32. Kholdeeva, O. A., Grigoriev, V. A., Maksimov, G. M., Fedotov, M. A.,
Golovin, A. V., and Zamaraev, K. I., J. Mol. Catal. A: Chem. 114,
123–130 (1996).