On the reaction of anthranilic acid with thionyl chloride: The actual structure of 'Kametani's sulfinamide anhydride'

DOI: 10.1016/S0040-4039(00)79739-5

Source and publish data:

Tetrahedron Letters p. 3263 - 3264 (1991)

Update date:2022-08-17

Topics:

Authors:

Garin Garin

Merino Merino

Orduna Orduna

Tejero Tejero

Uriel Uriel

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Article abstract of DOI:10.1016/S0040-4039(00)79739-5

Despite previous reports, no sulfinamide anhydride is formed from the reaction of anthranilic acid with thionyl chloride, the actual product being 2-sulfinylaminobenzoyl chloride. This excludes iminoketene formation in the reactions of this activated form

Full text of DOI:10.1016/S0040-4039(00)79739-5

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