Destannylative acylation of 1-[(2-methoxyethoxy)methoxy]-2- (phenylsulfonyl)-2-(tributylstannyl)cyclopropane: A novel route to 3- acylfurans

DOI: 10.1016/0040-4039(96)00852-0

Source and publish data:

Tetrahedron Letters p. 4585 - 4588 (1996)

Update date:2022-08-11

Topics:

Authors:

Pohmakotr, Manat

Takampon, Auntika

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)00852-0

Destannylative acylation of 1-[(2-methoxyethoxy)methoxy]-2- (phenylsulfonyl)-2-(tributylstannyl)cyclopropane (1) provided dihydrofurans 5 in good yields, which upon treatment with BF₃.OEt₂ in CH₂Cl₂ led to the formation of 3-acylfurans 6 in moderate yields. The reaction was proposed to proceed via the intramolecular Prins-type reaction of the oxonium intermediate 7.

Full text of DOI:10.1016/0040-4039(96)00852-0

Products guided by the article

Product name:Phenyl(3-furyl) ketone

Cas No:6453-98-1

R&D Labs maybe for 6453-98-1

Liaoning Yufeng Chemical Co.,Ltd.

Contact:86-0419-3418888

Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China
Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin
shanghai jiuling chemical co.,ltd.

Contact:+86-21-50387295

Address:Zaozhuang Road, Pudong, Shanghai City. China

Relevant to this article

Preparation, solid-state structure, and synthetic applications of isolable and storable haloalkylzinc reagents [1]

Doi:10.1021/ja994371v
(2000)
Supramolecular Hydrogels Based on Minimalist Amphiphilic Squaramide–Squaramates for Controlled Release of Zwitterionic Biomolecules

Doi:10.1002/chem.201701029
(2017)
Tandem overman rearrangement and intramolecular amidomercuration reactions. Stereocontrolled synthesis of cis- and frans-2,6-dialkylpiperidines

Doi:10.1021/ol048961w
(2004)
Doi:10.1021/ja01621a054
(1955)
SYNTHESIS AND TRANSFORMATIONS OF POLYHEDRAL COMPOUNDS. 14. OPENING OF HEXAHYDROPYRIMIDINE RING OF 2-SUBSTITUTED 1,3-DIAZAADAMANTANES BY ELECTROPHILIC REAGENTS

Doi:10.1007/BF00474490
(1992)
Formation of halocarbons in the methane-alkaline halide crystal system under UV radiation

Doi:10.1007/BF02494495
(1998)

Article Doi