Journal of the American Chemical Society p. 9015 - 9020 (1993)
Update date:2022-08-30
Topics:
Nakamura, Eiichi
Tanaka, Koichi
Fujimura, Tsutomu
Aoki, Satoshi
Williard, Paul G.
Michael addition of a metal enolate to a Fischer vinyl carbene complex 1 takes place with syn-diastereoselectivity. The resulting anion 2 can be trapped stereoselectively to afford a carbene complex 3 with stereocontrol of three contiguous stereogenic cen
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