Tetrahedron Letters p. 3831 - 3834 (1991)
Update date:2022-08-11
Topics:
Capdevielle, Patrice
Maumy, Michel
Title compound 1 is selectively hydroxytated in α position by three distinct copper- containing oxidant systems, involving dioxygen, peroxide anion or trimethylamine oxide. Trivalent copper is likely the key intermediate in this first reported model for the PHM activity of enzyme PAM.
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